Coordination chemistry of anticrowns. Synthesis and structure of the binuclear complex of perfluorinated three-mercury anticrown (o-F6Hg)3 with 1,2-dichloroethane

被引：0
作者：
K. I. Tugashov
S. M. Yunusov
E. S. Kalyuzhnaya
F. M. Dolgushin
I. A. Tikhonova
V. B. Shur
机构：
[1] Russian Academy of Sciences,A. N. Nesmeyanov Institute of Organoelement Compounds
来源：
Russian Chemical Bulletin | 2020年 / 69卷
关键词：
anticrowns; macrocyclic multidentate Lewis acids; polymercuramacrocycles; dihaloalkanes; complexes; mercury; X-ray diffraction analysis; 1,2-dichloroethane; organomercury compounds;
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摘要：
The reaction of perfluorinated three-mercury anticrown (o-C6F4Hg)3 (1) with 1,2-dichloroethane (DCE) affords the complex {[(o-C6F4Hg)3]2(ClCH2CH2Cl)}(2) containing two anticrown molecules per DCE molecule. According to the X-ray diffraction data, the DCE molecule in complex 2 acts as a bridge between molecules 1, each DCE chlorine atom being coordinated to a single mercury center of the neighboring anticrown molecules.
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页码：1092 / 1095
页数：3
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