A nitrate-selective microelectrode based on a lipophilic derivative of iodocobalt(III)salen

被引：0
|
作者：
P. G. Verschuren
Juul L. van der Baan
Rolf Blaauw
Dirk de Beer
Johannes C. van den Heuvel
机构：
[1] Instituut voor Technische Scheikunde,
[2] Universiteit van Amsterdam,undefined
[3] Nieuwe Achtergracht 166,undefined
[4] 1018 WV Amsterdam,undefined
[5] The Netherlands,undefined
[6] Scheikundig Laboratorium,undefined
[7] Vrije Universiteit,undefined
[8] De Boelelaan 1083,undefined
[9] 1081 HV Amsterdam,undefined
[10] The Netherlands,undefined
[11] Max-Planck-Institut für Marine Microbiology,undefined
[12] Celciusstraße 1,undefined
[13] 28359 Bremen,undefined
[14] Germany,undefined
来源：
Fresenius' Journal of Analytical Chemistry | 1999年 / 364卷
关键词：
Nitrate; Cobalt; Detection Limit; Nitrite; HCO3;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The synthesis of iodo{2,2′-[1,2-octadecanediylbis(nitrilomethylidyne)]diphenolato}cobalt is described. Liquid membrane microelectrodes based on this carrier exhibit Nernstian behaviour with a selectivity sequence according to the Hofmeister series: I– > NO3– > NO2– > Cl– > HCO3– > AcO–. The selectivity coefficient of nitrate over nitrite and chloride amounts to –1.6 and –2.7, respectively. The detection limit for nitrate in water amounts to 10–5.2 mol/L. A nitrate profile measured in a nitrifying biofilm is presented as a practical application.
引用
收藏
页码：595 / 598
页数：3
相关论文
共 50 条
  • [31] Novel Pr(III)-selective membrane sensor based on a new hydrazide derivative
    Ganjali, MR
    Mirnaghi, F
    Norouzi, P
    Adib, M
    SENSORS AND ACTUATORS B-CHEMICAL, 2006, 115 (01) : 374 - 378
  • [32] Lipophilic EDTA-based ligands in different diluents for the extraction of rare earths: Preliminary results with Nd(III), Dy(III) and Pr(III) in chloride and nitrate media
    Sukhbaatar, Tamir
    Piton, Raphaelle
    Giusti, Fabrice
    Arrachart, Guilhem
    Duvail, Magali
    Kumari, Aarti
    Daware, Santosh
    Gupta, Shally
    Goverapet, Sriram
    Sahu, Sushanta Kumar
    Rai, Beena
    Pellet-Rostaing, Stephane
    HYDROMETALLURGY, 2025, 231
  • [33] Al (III)-selective electrode based on newly synthesized xanthone derivative as neutral ionophore
    Yari, A
    Darvishi, L
    Shamsipur, M
    ANALYTICA CHIMICA ACTA, 2006, 555 (02) : 329 - 335
  • [34] A selective membrane electrode for Lanthanum(III) ion based on a hexaaza macrocycle derivative as ionophore
    Singh, Ashok Kumar
    Saxena, Puja
    Mehtab, Sameena
    Gupta, Barkha
    ANALYTICAL SCIENCES, 2006, 22 (10) : 1339 - 1344
  • [35] A Selective Membrane Electrode for Lanthanum(III) Ion Based on a Hexaaza Macrocycle Derivative as Ionophore
    Ashok Kumar Singh
    Puja Saxena
    Sameena Mehtab
    Barkha Gupta
    Analytical Sciences, 2006, 22 : 1339 - 1344
  • [36] Enantio selective epoxidation of non-functionalized alkenes using carbohydrate based salen-Mn(III) complexes
    Zhao, Shanshan
    Zhao, Jiquan
    Zhao, Dongmin
    CARBOHYDRATE RESEARCH, 2007, 342 (02) : 254 - 258
  • [37] Fluoride-selective polymeric membrane electrodes based on Zr(IV)- and Al(III)-salen ionophores of various structures
    Gorski, Lukasz
    Matusevich, Alexey
    Parzuchowski, Pawel
    Luciuk, Iwona
    Malinowska, Elzbieta
    ANALYTICA CHIMICA ACTA, 2010, 665 (01) : 39 - 46
  • [38] Ammonium- and nitrate-selective all-solid-state microelectrodes based on AgI-Ag2O-V2O5 glass transducer
    Maminska, Renata
    Kucharek, Marta
    Jozwiak, Pawel
    Garbarczyk, Jerzy
    Dybko, Artur
    Wroblewski, Wojciech
    CHEMIA ANALITYCZNA, 2006, 51 (06): : 899 - 908
  • [39] Highly selective chromogenic ionophores for the recognition of chromium(III) based on a water-soluble azocalixarene derivative
    Lu, LL
    Zhu, SF
    Liu, XZ
    Xie, ZZ
    Yan, X
    ANALYTICA CHIMICA ACTA, 2005, 535 (1-2) : 183 - 187
  • [40] A green extraction process for the selective recovery of Sc(III) based on hydrophobic betaine derivative ionic liquids
    Su, Xiang
    Liu, Huipeng
    Tian, Gang
    RSC ADVANCES, 2024, 14 (07) : 4853 - 4860
12345