1,3-Dipolar cycloaddition reaction of nitrone η6-(arene)chromium tricarbonyl complexes with styrene and η6-(styrene)chromium tricarbonyl

被引:0
|
作者
A. N. Artemov
E. V. Sazonova
N. Yu. Zarovkina
机构
[1] N. I. Lobachevsky State University of Nizhny Novgorod,
来源
Russian Chemical Bulletin | 2013年 / 62卷
关键词
nitrone; η; -(arene)chromium tricarbonyl; isoxazolidine; 1,3-dipolar cycloaddition;
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摘要
The products of 1,3-dipolar cycloaddition of the nitrone-type η6-(arene)chromium tricarbonyl complexes (CO)3CrC6H5CH=N+(O−)R, where R = Me, Ph, But, with styrene and η6-(styrene)chromium tricarbonyl were obtained and characterized by a combination of physicochemical methods. This type of reactions proceeded with very high regio- and stereoselectivity to exclusively form cis-2,3,5-tri-substituted isoxazolidines.
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页码:1382 / 1387
页数:5
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