Development of visible light-responsive N-doped TiO2/SiO2 core–shell nanoparticles for photocatalytic degradation of methylene blue dye

被引:0
作者
S. Samangsri
T. Areerob
S. Chiarakorn
机构
[1] King Mongkut’s University of Technology Thonburi,The Joint Graduate School of Energy and Environment
[2] PERDO,Center of Excellence On Energy Technology and Environment
[3] Prince of Songkla University Phuket Campus,Marine Environmental and Geoinformatics Technology Research Unit, Faculty of Technology and Environment
[4] King Mongkut’s University of Technology Thonburi,Environmental Technology Program, School of Energy, Environment and Materials
[5] King Mongkut’s University of Technology Thonburi,Environmental and Energy Management for Community and Circular Economy (EEC&C) Research Group
来源
Research on Chemical Intermediates | 2023年 / 49卷
关键词
Nitrogen-doped TiO; SiO; Photocatalysis; Core/shell nanoparticles; Visible light irradiation; Photodegradation;
D O I
暂无
中图分类号
学科分类号
摘要
A visible-light responsive Nitrogen-doped TiO2 photocatalyst (NT) is a promising photocatalyst for environmental applications. This study aimed to synthesize N-doped TiO2/SiO2 (NT/SiO2) core/shell nanoparticles and investigate the effect of SiO2 on the photocatalytic reactivity of NT. The NT photocatalyst was prepared by the solvothermal method, while the NT/SiO2 core/shell photocatalysts were prepared by the sol–gel method with and without the use of cetyltrimethylammonium bromide (CTAB) as a directing agent. The photocatalytic reactivity of the NT/SiO2 core/shell photocatalysts was examined by methylene blue (MB) photodegradation under light-emitting diode visible light irradiation. Transmission electron microscope images indicated the core/shell structure, in which NT was a core and mesoporous SiO2 was a shell. The bonding of NT and SiO2 was examined by X-ray Photoelectron Spectroscopy. Interestingly, using CTAB caused a decrease in the photocatalytic performance of NT/SiO2 due to the aggregation of NT particles. The results of MB photodegradation indicated that the NT/SiO2 core/shell catalysts (without CTAB) had higher MB photodegradation efficiency (72%) than that of the NT/CTAB/SiO2 core/shell catalysts (60%), and bare NT (30%), respectively. The role of the mesoporous SiO2 shell was not only to increase the specific surface area but also to decrease the recombination rate of photogenerated electrons and holes in the NT/SiO2 core/shell photocatalysts.
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页码:1649 / 1664
页数:15
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