Carbon Nanofibers Propped Hierarchical Porous SiOC Ceramics Toward Efficient Microwave Absorption

The hierarchical porous SiOC ceramics (HPSCs) have been prepared by the pyrolysis of precursors (the mixture of dimethicone and KH-570) and polyacrylonitrile nanofibers (porous template). The HPSCs possess hierarchical porous structure with a BET surface area of 51.4 m2/g and have a good anti-oxidation property (only 5.1 wt.% weight loss). Owing to the porous structure, the HPSCs deliver an optimal reflection loss value of − 47.9 dB at 12.24 GHz and an effective absorption bandwidth of 4.56 GHz with a thickness of 2.3 mm. The amorphous SiOC, SiOx, and free carbon components within SiOC make contributions to enhancing dipolar polarization. Besides, the abundant interfaces between SiOC and carbon nanofibers (CNFs) are favorable for improving interfacial polarization. The conductive loss arisen from cross-linked CNFs can also boost the microwave absorption performance.