Inhibitory effect of 2,6-di-tert-butylphenol groups in iron and manganese porphyrins on the catalytic activity in the oxidation of hydrocarbons by hydrogen peroxide

被引：5

作者：

Gerasimova O.A. ^{[1
]}

Shpakovskii D.B. ^{[1
]}

Milaeva E.R. ^{[1
]}

Louloudi M. ^{[1
,2
]}

Hadjiliadis N. ^{[1
,2
]}

机构：

[1] Organic Chemistry Department,

[2] University of Ioannina,undefined

来源：

Moscow University Chemistry Bulletin | 2007年 / 62卷 / 5期

关键词：

Porphyrin; Epoxide; Cyclooctene; Metalloporphyrin; Iron Porphyrin;

D O I：

10.3103/S0027131407050100

中图分类号：

学科分类号：

摘要：

Iron and manganese porphyrins containing 2,6-di-tert-butylphenyl groups (R4PFeCl and R4PMnCl) have been synthesized to be further immobilized on silica gels via various spacers. The activity of these porphyrins in the oxidation of alkanes and alkenes by hydrogen peroxide has been studied. 2,6-Di-tert-butylphenol groups decrease the catalytic activity of porphyrins in oxidation processes. © 2007 Allerton Press, Inc.

引用

页码：264 / 268

页数：4

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