A Theoretical Treatment of Charge-Transfer Interaction in an Aqueous Solution of Polyelectrolyte

被引：0

作者：

Yoshiya Kawabata

Tomoyuki Itaya

Kazuyoshi Ueda

Yuriko Aoki

Akira Imamura

机构：

[1] Kyushu University,Department of Applied Quantum Physics and Nuclear Engineering, Graduate School of Engineering

[2] Nagano National College of Technology,Laboratory of Chemistry, Department of General Education

[3] Yokohama National University,Division of Mechanical Engineering and Material Science, Graduate School of Engineering

[4] Hiroshima University,Department of Chemistry, Graduate School of Science

[5] Hiroshima Kokusai Gakuin University,Department of General Education, Faculty of Engineering

来源：

Polymer Journal | 2003年 / 35卷

关键词：

Charge-Transfer; Molecular Orbital Method; Polyelectrolyte; Counterion Binding;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Molecular orbital theory was adopted to explain theoretically the charge-transfer (CT) complexation of aromatic ions (donors) with 9,10-anthraquinone-2-sulfonate (acceptor) in an aqueous solution of polyelectrolyte. By the approximation of the theory, a distinct linear relation between the energies of the CT absorption band and ionization potentials of the donor molecules has been derived although the stoichiometric ratios of CT complexes which formed around the polyion were different.

引用

页码：573 / 577

页数：4

共 50 条

[1] A theoretical treatment of charge-transfer interaction in an aqueous solution of polyelectrolyte
Kawabata, Y
Itaya, T
Ueda, K
Aoki, Y
Imamura, A
POLYMER JOURNAL, 2003, 35 (07) : 573 - 577
[2] Effects of acceptor structure on charge-transfer complexation in aqueous polyelectrolyte solution
Kawabata, Y
Itaya, T
Sasaki, Y
Ochiai, H
Ueda, K
Imamura, A
POLYMER JOURNAL, 1997, 29 (03) : 211 - 217
[3] Effects of Acceptor Structure on Charge-Transfer Complexation in Aqueous Polyelectrolyte Solution
Yoshiya Kawabata
Tomoyuki Itaya
Yuki Sasaki
Hiroshi Ochiai
Kazuyoshi Ueda
Akira Imamura
Polymer Journal, 1997, 29 : 211 - 217
[4] CHARGE-TRANSFER COMPLEXATION IN AQUEOUS POLYELECTROLYTE SOLUTION .2. INTERACTION BETWEEN POLYCATIONS AND CT COMPLEXES
ITAYA, T
KAWABATA, Y
OCHIAI, H
UEDA, K
IMAMURA, A
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1994, 67 (08) : 2047 - 2052
[5] Charge-transfer complexation in an aqueous polyelectrolyte solution .3. Complexation between pyrenesulfonate or anthracenesulfonate and anthraquinonesulfonate ions
Kawabata, Y
Itaya, T
Sasaki, Y
Ochiai, H
Ueda, K
Imamura, A
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1996, 69 (09) : 2453 - 2459
[6] CHARGE-TRANSFER COMPLEXATION IN AQUEOUS POLYELECTROLYTE SOLUTION .1. COMPLEXATION BETWEEN DIMETHOXYANTHRACENESULFONATE ION AND ANTHRAQUINONESULFONATE ION
ITAYA, T
KAWABATA, Y
OCHIAI, H
UEDA, K
IMAMURA, A
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1994, 67 (06) : 1538 - 1543
[7] CHARGE-TRANSFER INTERACTION IN TRIPLET QUENCHING OF NAPHTHALENES IN SOLUTION
ANDER, S
BLUME, H
HEINRICH, G
SCHULTEF.D
CHEMICAL COMMUNICATIONS, 1968, (13) : 745 - &
[8] Charge-transfer interaction between bipyridinium and naphthyl groups of optically active viologens in an aqueous solution
Tsukahara, K.
Kaneko, J.
Miyaji, T.
Abe, K.
Tetrahedron Letters, 37 (18):
[9] Charge-transfer interaction between bipyridinium and naphthyl groups of optically active viologens in an aqueous solution
Tsukahara, K
Kaneko, J
Miyaji, T
Abe, K
TETRAHEDRON LETTERS, 1996, 37 (18) : 3149 - 3152
[10] THEORETICAL TREATMENT OF CHARGE-TRANSFER REACTIONS IN POLAR LIQUIDS
KUZNETSO.AM
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY,USSR, 1970, 44 (03): : 467 - &

← 1 2 3 4 5 →