Synthesis of optically active omeprazole by catalysis with vanadyl complexes with chiral Schiff bases

被引：0
|
作者：
E. A. Koneva
T. M. Khomenko
S. Yu. Kurbakova
N. I. Komarova
D. V. Korchagina
K. P. Volcho
N. F. Salakhutdinov
A. G. Tolstikov
G. A. Tolstikov
机构：
[1] Novosibirsk State University,N. N. Vorozhtsov Institute of Organic Chemistry
[2] Siberian Branch of the Russian Academy of Sciences,G. K. Boreskov Institute of Catalysis
[3] Siberian Branch of the Russian Academy of Sciences,undefined
来源：
Russian Chemical Bulletin | 2008年 / 57卷
关键词：
esomeprazole; omeprazole; asymmetric oxidation; sulfides; chiral sulfoxides; chiral ligands; Schiff bases; vanadium complexes; metal complex catalysis;
D O I：
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中图分类号：
学科分类号：
摘要：
A new method for the preparation of optically active omeprazole, consisting in asymmetric oxidation of the corresponding sulfide with the use of vanadyl complexes with chiral Schiff bases as the catalysts has been elaborated. The best results of the oxidation were achieved by the use of the combination VO(acac)2—2-[{(1S,2S,3R,5S)-3-hydroxymethyl-2,6,6-trimethyl-bicyclo[3.1.1]hept-2-ylimino}methyl]phenol—N-ethyl-N,N-diisopropylamine.
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页码：1680 / 1685
页数：5
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