Elemental Impurity Composition of High-Purity Volatile Hydrides and Chlorides

被引:0
作者
O. P. Lazukina
K. K. Malyshev
E. N. Volkova
M. F. Churbanov
机构
[1] Russian Academy of Sciences,Devyatykh Institute of Chemistry of High
来源
Inorganic Materials | 2018年 / 54卷
关键词
purity level; detection limits;
D O I
暂无
中图分类号
学科分类号
摘要
We have calculated the total elemental composition and assessed its statistical characteristics for two classes of high-purity volatile substances—inorganic hydrides and chlorides—using Exhibition–Collection of Extrapure Substances data. The average and total contents of elemental impurities in the purest samples of compounds of these classes have been estimated. Using the division of elemental impurities into classes, we have estimated the contributions of individual classes to the total impurity content in arrays of hydride and chloride samples. The use of these calculation techniques makes it possible to more accurately characterize the impurity composition of individual samples and arrays of samples on the whole, refining statistical characteristics of the description of the impurity composition.
引用
收藏
页码:176 / 186
页数:10
相关论文
共 66 条
[1]  
Malyshev K.K.(1990)Statistical estimation of the total impurity concentration from incomplete analytical data, illustrated by the examples of tellurium, manganese, and aluminum Vysokochist. Veshchestva 2 229-236
[2]  
Stepanov V.M.(1992)Assessment of the total impurity composition of solid elemental substances Vysokochist. Veshchestva 5–6 54-63
[3]  
Devyatykh G.G.(2001)Reliability and completeness of data on the impurity composition of highpurity volatile compounds Inorg. Mater. 37 302-305
[4]  
Kovalev I.D.(2008)An evaluation of the purity of volatile compounds on the elemental composition of impurities Inorg. Mater. 44 1266-1271
[5]  
Makarov Yu.B.(2016)A new technique for estimating the average and total impurity concentrations in samples of high-purity substances Inorg. Mater. 52 313-323
[6]  
Osipova L.I.(2011)Identification of impurities in silane of natural isotopic composition and enriched with Anal. Kontrol 5 421-428
[7]  
Stepanov V.M.(2015)Si by gas chromatography/ mass spectrometry Inorg. Mater. 51 965-971
[8]  
Yan’kov S.V.(2017)Composition of molecular impurities in high-pure germane Inorg. Mater. 56 1-8
[9]  
Devyatykh G.G.(2010)Impurity composition of high-purity isotopically enriched monosilane and monogermane Zavod. Lab., Diagn. Mater. 76 13-17
[10]  
Kovalev I.D.(2011)Gas chromatography/mass spectrometry analysis of high-purity arsine J. Anal. Chem. 66 634-640