Regioisomeric acetoxy derivatives of 8-aza-D-homogona-12,17a-dione. Annelation of 1-methyl-3,4-dihydroisoquinoline with 4-acetoxy-2- acetylcyclohexane-1,3-dione

被引:0
作者
Gulyakevich O.V. [1 ]
Zaitsev V.G. [1 ]
Mikhal'chuk A.L. [1 ]
机构
[1] Institute of Bioorganic Chemistry, National Academy of Sciences
关键词
2-acylcyclohexane-1,3-diones; 3,4-dihydroisoquinolines; 8-aza-D-homogonanes; 8-azasteroids; Annelation; Cyclic Schiffs bases; Regioselectivity; Stereochemistry;
D O I
10.1023/B:COHC.0000028627.77366.49
中图分类号
学科分类号
摘要
Annelation ([2+4] cyclocondensation) of 1-methyl-3,4-dihydroisoquinoline with 4-acetoxy-2-acetylcyclohexane-1,2-dione leads to a mixture of regioisomeric acetoxy derivatives of 9-methyl-8-aza-D-homogona-12,17a-dione.
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页码:315 / 319
页数:4
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