Crystal Structure of (H3O)4[(C2H5)4N]6 [Th2Cl4(H2O)12O]3[Re4Se4(CN)12]4

被引：0
作者：
O. A. Efremova
Yu. V. Mironov
N. V. Kuratieva
K.-K. Wang
V. E. Fedorov
机构：
[1] Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division
[2] Novosibirsk State University,undefined
来源：
Journal of Structural Chemistry | 2010年 / 51卷
关键词：
cluster; rhenium; chalcocyano; bridging oxygen atom; thorium; crystal structure;
D O I：
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摘要：
Crystals of the rhenium cluster complex (H3O)4[(C2H5)4N]6[Th2Cl4(H2O)12O]3[Re4Se4(CN)12]4 are obtained in an acidic (HCl) aqueous solution by the reaction of cluster salt K4[Re4Se4(CN)12]·6H2O with ThCl4 and (C2H5)4NCl. Single crystal X-ray analysis shows that the title compound is ionic and crystallizes in the cubic crystal system (a = 22.7322(3) Å, V = 11746.93(27) Å3, Z = 2, I4 3m space group, R = 0.0350). It contains [Th2Cl4(H2O)12O]2+ cations with two thorium atoms bonded to each other through the bridging oxygen atom forming an angle of 180° in the structure.
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页码：782 / 784
页数：2
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