Synthesis and spectroscopic properties of novel polynuclear molybdenum(VI) peroxo complexes containing amino acids

被引：0

作者：

Katarzyna Serdiuk

Roman Gancarz

Maria Cieślak-Golonka

机构：

[1] Pedagogical University,Institute of Chemistry

[2] The University of Technology,Institute of Organic Chemistry, Biochemistry and Biotechnology

[3] The University of Technology,Institute of Inorganic Chemistry and Metallurgy of Rare Elements

来源：

Transition Metal Chemistry | 2001年 / 26卷

关键词：

Precipitation; H2O2; Inorganic Chemistry; Glycine; Serine;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The interaction of an aqueous MoO3 solution with H2O2, and glycine, serine, lysine, histidine or methionine, results in the precipitation of mononuclear MoO(O2)2LH2O (L = glycine), dinuclear Mo2O4(O2)2L(H2O)4 (L = methionine, serine) and trinuclear Mo3O7(O2)2L(H2O)6 (L = lysine, histidine) species. A detailed analysis of the electronic spectra has been performed using the digital filter method. It was found that the polynuclear complexes preserve the individuality of the molybdenum oxo peroxo core.

引用

页码：538 / 543

页数：5

共 33 条

[31] A novel (E,E)-dioxime and its mono-, di- and trinuclear complexes bearing tetradentate octyl sulfanyl phenylamino substituents. Synthesis, characterization and electrochemical properties of its transition metal complexes [J].

Mehmet Kandaz ;

Seher Zerrin Çoruhlu ;

İsmail Yilmaz ;

Ali Rıza Özkaya .

Transition Metal Chemistry, 2002, 27 :877-883

[32] Synthesis, properties, and crystal structure of a novel 3-hydroxy-(4H)-benzopyran-4-one containing copper(II) complex, and its oxygenation and relevance to quercetinase [J].

József Kaizer ;

József Pap ;

Gábor Speier ;

Marius Réglier ;

Michel Giorgi .

Transition Metal Chemistry, 2004, 29 :630-633

[33] Synthesis, crystal structure, and properties of [Cu(LH)]2[M(mnt)2] [M = Ni or Cu; H2L = 3,3′-(1,3-propanediyldinitrilo)-bis(2-butanone oxime); mnt2− = maleonitriledithiolate] complexes containing bridging cyano groups [J].

Xiaoming Ren ;

Chunying Duan ;

Huizhen Zhu ;

Qingjin Meng ;

Chuanjiang Hu ;

Changsheng Lu ;

Yongjiang Liu .

Transition Metal Chemistry, 2001, 26 :295-299

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