Synthesis and spectroscopic properties of novel polynuclear molybdenum(VI) peroxo complexes containing amino acids

被引：0
|
作者：
Katarzyna Serdiuk
Roman Gancarz
Maria Cieślak-Golonka
机构：
[1] Pedagogical University,Institute of Chemistry
[2] The University of Technology,Institute of Organic Chemistry, Biochemistry and Biotechnology
[3] The University of Technology,Institute of Inorganic Chemistry and Metallurgy of Rare Elements
来源：
Transition Metal Chemistry | 2001年 / 26卷
关键词：
Precipitation; H2O2; Inorganic Chemistry; Glycine; Serine;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The interaction of an aqueous MoO3 solution with H2O2, and glycine, serine, lysine, histidine or methionine, results in the precipitation of mononuclear MoO(O2)2LH2O (L = glycine), dinuclear Mo2O4(O2)2L(H2O)4 (L = methionine, serine) and trinuclear Mo3O7(O2)2L(H2O)6 (L = lysine, histidine) species. A detailed analysis of the electronic spectra has been performed using the digital filter method. It was found that the polynuclear complexes preserve the individuality of the molybdenum oxo peroxo core.
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页码：538 / 543
页数：5
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