Influences of Ru-doping on the magnetic properties of Ca0.85Pr0.15Mn1−xRuxO3

被引:0
|
作者
T. L. Phan
Y. D. Zhang
S. C. Yu
P. Q. Thanh
P. D. H. Yen
机构
[1] Chungbuk National University,BK
[2] Vietnam National University,21 Program and Department of Physics
来源
Journal of the Korean Physical Society | 2012年 / 61卷
关键词
Ru-doped perovskite manganites; Magnetic properties;
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学科分类号
摘要
CaMnO3 is an antiferromagnet, in which the super-exchange interaction taking place between Mn4+ ions plays an important role. The doping of a small amount of 15% Pr into the Ca site, Ca0.85Pr0.15MnO3, leads to the appearance of Mn3+ ions, and introduces the ferromagnetic (FM) double-exchange interaction between Mn3+ and Mn4+ ions, which is dominant in a narrow temperature range of 90 ∼ 115 K. The FM interaction becomes strong for Ca0.85Pr0.15MnO3 doped with 4 and 8% Ru into the Mn site (i.e., Ca0.85Pr0.15Mn1−xRuxO3 with x = 0.04 and 0.08). The Curie temperature obtained for x = 0.04 and 0.08 are about 135 and 180 K, respectively. While the FM interaction in the former is dominant due to Mn3+-Mn4+ exchange pairs, the latter has the contribution of Ru ions. This results in remarkable differences in the features of their FM-paramagnetic phase transitions and their coercive fields Hc.
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页码:1568 / 1572
页数:4
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