Small angle X-ray scattering studies of nanocellular and nanoporous structures

被引:0
作者
Hideaki Yokoyama
机构
[1] Graduate School of Frontier Sciences,Department of Advanced Materials Science
[2] The University of Tokyo,undefined
来源
Polymer Journal | 2013年 / 45卷
关键词
carbon dioxide; GISAXS; SAXS; nanocell; nanopore; SAXS; thin film;
D O I
暂无
中图分类号
学科分类号
摘要
Recently, closed cellular and open porous structures on the nanometer scale have been attracting much attention. Our group has developed a novel method for producing such nanocellular and nanoporous structures using a block copolymer as a template and supercritical carbon dioxide. Small angle X-ray scattering (SAXS) has an important role in characterizing nanocells and nanopores. In particular, grazing incidence SAXS reveals embedded nanocellular and nanoporous structures in thin films. In addition, SAXS can be used for in situ measurements to study the process of nanocellular and nanoporous formation in supercritical carbon dioxide. In this focused review, our recent progress on nanocellular and nanoporous fabrication and the use of SAXS techniques to characterize such structures will be presented.
引用
收藏
页码:3 / 9
页数:6
相关论文
共 257 条
[1]  
Lee SB(2002)Antibody-based bio-nanotube membranes for enantiomeric drug separations Science 296 2198-2200
[2]  
Mitchell DT(2004)DNA-functionalized nanotube membranes with single-base mismatch selectivity Science 305 984-986
[3]  
Trofin L(2003)Mesoporous templated silicates: an overview of their synthesis, catalytic activation and evaluation of the stability Adv. Colloid Interface Sci 103 121-147
[4]  
Nevanen TK(2005)Thin-film transformations and volatile products in the formation of nanoporous low-k polymethylsilsesquioxane-based dielectric J. Vac. Sci. Technol. B 23 908-917
[5]  
Soederlund H(1992)Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism Nature 359 710-712
[6]  
Martin CR(1998)Generalized syntheses of large-pore meosporous metal oxides with semicrystalline frameworks Nature 396 152-155
[7]  
Kohli P(1996)Free-standing and oriented mesoporous silica films grown at the air–water interface Nature 381 589-592
[8]  
Harrell CC(2006)Hexagonal mesoporous germanium Science 313 817-820
[9]  
Cao ZH(2002)An ordered mesoporous organosilica hybrid material with a crystal-like wall structure Nature 416 304-307
[10]  
Gasparac R(2006)Hexagonal nanoporous germanium through surfactant-driven self-assembly of Zintl clusters Nature 441 1126-1130