Effect of using batch or semi-batch reactor on the chemical composition distribution of styrene-maleic anhydride-acrylonitrile terpolymers

被引:0
|
作者
De J. S. Cunha R. [1 ]
Gomes A.S. [2 ]
机构
[1] Instituto de Química-UFBA, Camp. Universitário de Ondina
[2] Inst. de Macromoléculas-UFRJ, 21945-970 Rio de Janeiro-RJ
关键词
Mole Fraction; Maleic Anhydride; Volumetric Titration; Composition Distribution; Reactive Monomer;
D O I
10.1007/s002890050093
中图分类号
学科分类号
摘要
The influence of the reactor type on distribution of chemical composition of ST/AN/MA terpolymers obtained by free-radical polymerization is shown. When a batch reactor was used we have obtained polymers with broad chemical composition distribution. However, if a semi-batch reactor with appropriate addition protocol was used it can be possible to synthesize terpolymers with homogeneous chemical composition.
引用
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页码:595 / 600
页数:5
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