Effect of alkali metal oxides on the selectivity of carbon monoxide conversion to give hydrogen on copper-containing catalysts

被引：0
|
作者：
Yu. M. Komarov
A. A. Il’in
N. N. Smirnov
A. P. Il’in
D. B. Babaikin
机构：
[1] Ivanovo State University of Chemical Technology,
来源：
Russian Journal of Applied Chemistry | 2013年 / 86卷
关键词：
Methyl Formate; Methyl Acetate; Mechanochemical Activation; Ammonium Carbonate; Cesium Carbonate;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Possibility of synthesizing aluminum-zinc-copper catalysts by mechanochemical activation of metallic copper and zinc with ammonium carbonate, followed by introduction of γ-Al2O3 and promoter additives (potassium, rubidium, and cesium carbonates), hydrothermal treatment, and calcination is demonstrated. The effect of the promoter additives and preparation conditions was studied. The activity and selectivity of the samples in the reaction of steam conversion of CO was examined. The composition of by-products formed in the course of a test reaction was determined.
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页码：27 / 31
页数：4
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