Synthesis, crystal structures and catalytic properties of copper(II) and cobalt(II) coordination polymers based on a flexible benzimidazole ligand

被引：0
作者：
Jian-chen Geng
Li Qin
Cui-hong He
Guang-hua Cui
机构：
[1] Hebei United University,College of Chemical Engineering
来源：
Transition Metal Chemistry | 2012年 / 37卷
关键词：
Benzimidazole; Methyl Orange; Coordination Polymer; Lattice Water Molecule; Methyl Orange Solution;
D O I：
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学科分类号：
摘要：
Two coordination polymers, namely [Cu(L)2]·(NO3)2 (1) and [Co(L)(chdc)]·2H2O (2) [(chdc = 1,4-cyclohexanedicarboxylate, L = 1,3-bis-(5,6-dimethylbenzimidazole-1-yl-methylene)-benzene], based on a flexible 5,6-dimethylbenzimidazole ligand have been synthesized and characterized by physico-chemical and spectroscopic methods and single-crystal diffraction. Complex 1 shows a 2D (4,4) network structure linked by L ligands while complex 2 displays a 1D ladder-like chain bridged by L and chdc ligands. The catalytic activities of both complexes for the degradation of methyl orange have been investigated.
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页码：579 / 585
页数：6
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