PtcoreAgshell nanoparticle-catalyzed reduction of methylviologene with hydrogen in aqueous solution

被引:0
作者
E. V. Abkhalimov
B. G. Ershov
机构
[1] Russian Academy of Sciences,Frumkin Institute of Physical Chemistry and Electrochemistry
来源
Colloid Journal | 2010年 / 72卷
关键词
Methylviologene; Colloid Journal; Platinum Nanoparticles; Transmission Elec Tron Microscope Data; Silver Layer;
D O I
暂无
中图分类号
学科分类号
摘要
Bimetallic PtcoreAgshell nanoparticles demonstrate the ability to catalyze methylviologene reduction with hydrogen in water-alkali solutions, which is inherent in platinum nanoparticles. The onset of the reaction is preceded by an induction period whose duration increases with the thickness of a silver layer covering a platinum core. The reaction slows down with a rise in the thickness of the silver layer. The mechanism of catalysis is discussed.
引用
收藏
页码:441 / 445
页数:4
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