Temperature dependence of the viscous flow of glass-forming melts in a broad temperature range

被引:0
作者
D. S. Sanditov
S. B. Munkueva
机构
[1] Buryat State University,Institute of Physical Material Science
[2] Russian Academy of Sciences,undefined
来源
Glass Physics and Chemistry | 2016年 / 42卷
关键词
viscous flow; model; glass and its melts; delocalization of an atom; structural change; bridge atom;
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摘要
An equation which is able to describe the temperature dependence of the viscous flow of glassforming melts in a broad range, including the glass-transition range and elevated temperatures has been obtained. The equation contains three parameters; one of them is the preexponential multiplier, which is defined by the extension of the viscosity curve to elevated temperatures (using the Lagrange polynomial), and the other two, the delocalization energy of the atom and the transition potential of the particle, are adjustable parameters. The delocalization energy of the atom that is determined by adjustment is in sufficient accordance with the calculation according to the model of delocalized atoms. The nature of the viscous flow of glass and its melts is discussed.
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页码:135 / 140
页数:5
相关论文
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