X-Ray Diffraction Analysis of Aluminum Hexamolybdenocobaltate(III) and Hexamolybdenocromate(III)

被引：0
作者：
G. Z. Kaziev
Saul O. Quinones
V. K. Bel'skii
V. I. Zavodnik
I. V. Osminkina
Antonio De Ita
机构：
[1] Moscow State Pedagogical University,
[2] Mexican State University,undefined
[3] Karpov Institute of Physical Chemistry,undefined
来源：
Russian Journal of Coordination Chemistry | 2002年 / 28卷
关键词：
Aluminum; Physical Chemistry; Diffraction Analysis; Cell Parameter; Unit Cell Parameter;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Isostructural crystals of aluminum hexamolybdenocobaltate(III) and hexamolybdenocromate(III) Al[MMo6O18(OH)6] · 16H2O (M = Co(III) and Cr(III)) were studied using X-ray diffraction analysis. These compounds crystallize in the triclinic system: space group P\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document} $$\overline 1$$ \end{document}, Z = 1, ρ(calcd) = 2.665 and 2.611 g/cm3, respectively. The unit cell parameters were determined: for aluminum hexamolybdenocobaltate(III), a = 6.796(1) Å, b= 11.248(2) Å, c = 11.568(2) Å; α = 101.36(2)°, β = 96.95(2)°, γ = 102.23(2)°; for aluminum hexamolybdenocromate(III), a = 6.838(1) Å, b = 11.312(2) Å, c = 11.605(2) Å; α = 101.29(3)°, β = 97.13(3)°, γ = 102.15(3)°.
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页码：384 / 388
页数：4
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