ESR and solid-state natural abundance 13C CP/MAS NMR study of crystalline alkyl (R = C2H5, i-C3H7, i-C4H9, s-C4H9, and C5H11) xanthate copper(II) and thallium(I) complexes

被引：0

作者：

A. V. Ivanov

O. A. Bredyuk

O. N. Antzutkin

W. Forsling

机构：

[1] Russian Academy of Sciences,Amur Institute of Integrated Research, Far East Division

[2] Blagoveshchensk State Pedagogical University,undefined

[3] Luleå University of Technology,undefined

来源：

Russian Journal of Coordination Chemistry | 2005年 / 31卷 / 1期

关键词：

Copper; Spectroscopy; Physical Chemistry; Inorganic Chemistry; Thallium;

D O I：

10.1007/PL00022088

中图分类号：

学科分类号：

摘要：

Crystalline thallium(I) alkylxanthate complexes [Tl{S(S)COR}]n (R = C2H5, i-C3H7, i-C4H9, s-C4H9, and C5H11) and isotope-substituted heteropolynuclear Cu(II)Tl(I) complexes [63(65)CuTl6(S2COR)8] (R= i-C4H9 and C5H11) were obtained and studied by ESR and high-resolution solid-state 13C CP/MAS NMR spectroscopy. According to the 13C NMR data, polynuclear thallium(I) complexes contain structurally equivalent alkylxanthate ligands. The ESR study revealed the Jahn-Teller dynamic effect in Cu(II)Tl(I) complexes; the nuclei of six Tl atoms are involved in the hyperfine interaction.

引用

页码：45 / 50

页数：5

共 50 条

[1] ESR and solid-state natural abundance 13C CP/MAS NMR study of crystalline alkyl (R = C2H5, i-C3H7, i-C4H9, s-C4H9, and C5H11) xanthate copper(II) and thallium(I) complexes
A. V. Ivanov
O. A. Bredyuk
O. N. Antzutkin
W. Forsling
Russian Journal of Coordination Chemistry, 2005, 31 : 45 - 50
[2] ESR and solid-state natural abundance 13C CP/MAS NMR study of crystalline alkyl (R =C2H5, i-C3H7 i-C4H9,s-C4H9, and C5H11) xanthate copper(II) and thallium(I) complexes
Ivanov, AV
Bredyuk, OA
Antzutkin, ON
Forsling, W
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2005, 31 (01) : 45 - 50
[3] Copper(II) and nickel(II) alkylxanthate complexes (R =C2H5, i-C3H7, i-C4H9, s-C4H9, and C5H11):: EPR and solid-state 13C CP/MAS NMR studies
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[4] Copper(II) and Nickel(II) Alkylxanthate Complexes (R = C2H5, i-C3H7, i-C4H9, s-C4H9, and C5H11): EPR and Solid-State 13C CP/MAS NMR Studies
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[5] KINETICS AND THERMOCHEMISTRY OF THE REACTIONS OF ALKYL RADICALS (CH3, C2H5, I-C3H7, S-C4H9, AND T-C4H9) WITH HI - A RECONCILIATION OF THE ALKYL RADICAL HEATS OF FORMATION
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[6] ENTHALPIES OF FORMATION OF [MO(ETA-C5H5)2(SR)2] COMPLEXES - R=N-C3H7, I-C3H7, N-C4H9, OR T-C4H9
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[9] RATE CONSTANTS FOR THE REACTIONS OF CH3 RADICALS WITH C2H5, I-C3H7 AND T-C4H9 RADICALS
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[10] RATE CONSTANTS FOR THE REACTION OF CH3 RADICALS WITH C2H5, I-C3H7 AND T-C4H9 RADICALS
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