Kinetics of Decomposition of Hydrogen Peroxide in the Presence of Mono- and Heteropolynuclear Complexes of Cu2+ and Co2+/3+ with Deprotonated Di- and Triethanolamines

被引：0
作者：
O. A. Levchenko
V. A. Kotseruba
D. G. Chikhichin
V. G. Makhankova
O. Yu. Vasilyeva
E. A. Buvaylo
V. N. Kokozay
G. L. Kamalov
机构：
[1] National Academy of Sciences of Ukraine,A. V. Bogatsky Physicochemical Institute
[2] Taras Shevchenko National University of Kyiv,undefined
来源：
Theoretical and Experimental Chemistry | 2018年 / 53卷
关键词：
heterometallic chelates; di- and triethanolamines; hydrogen peroxide; catalyst; isokinetic relationship;
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摘要：
Features of the decomposition of H2O2 in the presence of polynuclear complexes with Co2Cu2 and Co3Cu2 metal cores with deprotonated and di- and triethanolamines (H2Dea and H3Tea), compounds with the composition (H2Tea)ConCumCl (m + n =1; n = 0.33, 0.5, 0.67), and mononuclear complexes (H2Tea)CuCl and (H2Tea)CoCl were examined. It is suggested that the reaction in the presence of poly- and mononuclear complexes has different mechanisms.
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页码：402 / 409
页数：7
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  • [1] Kinetics of Decomposition of Hydrogen Peroxide in the Presence of Mono- and Heteropolynuclear Complexes of Cu2+ and Co2+/3+ with Deprotonated Di- and Triethanolamines
    Levchenko, O. A.
    Kotseruba, V. A.
    Chikhichin, D. G.
    Makhankova, V. G.
    Vasilyeva, O. Yu.
    Buvaylo, E. A.
    Kokozay, V. N.
    Kamalov, G. L.
    THEORETICAL AND EXPERIMENTAL CHEMISTRY, 2018, 53 (06) : 402 - 409
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