Enzymatic Synthesis of Aromatic Polyesters by Lipase-Catalyzed Polymerization of Dicarboxylic Acid Divinyl Esters and Glycols

被引：0
作者：
Hiroshi Uyama
Shigeru Yaguchi
Shiro Kobayashi
机构：
[1] Kyoto University,Department of Materials Chemistry, Graduate School of Engineering
[2] Tohoku University,Department of Materials Chemistry, Graduate School of Engineering
来源：
Polymer Journal | 1999年 / 31卷
关键词：
Enzymatic Polymerization; Lipase; Aromatic Polyester; Divinyl Ester; Polycondensation;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Polyesters containing aromatic moiety in the main chain have been synthesized by enzymatic polymerization of dicarboxylic acid divinyl esters and glycols under mild reaction conditions. Divinyl esters of isophthalic acid, terephthalic acid, and p-phenylene diacetic acid, were used as new monomer for the enzymatic polymerization. Effects of the polymerization conditions were systematically investigated in the polymerization of divinyl isophthalate and 1,6-hexanediol. Candida antarctica lipase afforded the polymer of the highest molecular weight. Methylene chain length of the glycol affected the polymer yield and molecular weight. Divinyl terephthalate was enzymatically polymerized under the similar reaction conditions, yielding the polymer of lower molecular weight. Enzymatic polymerization of divinyl sebacate and p-xylylene glycol also afforded the aromatic polyester.
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页码：380 / 383
页数：3
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