Synthesis and crystal structure of 1-(4-fluorophenyl)-and 1-(4-dimethylamino)phenylgermatranes

被引：0
作者：
E. Lukevics
L. Ignatovich
T. Shul’ga
S. Belyakov
机构：
[1] Latvian Institute of Organic Synthesis,
来源：
Chemistry of Heterocyclic Compounds | 2008年 / 44卷
关键词：
germatranes; crystal structure; synthesis; transannular N→Ge bond;
D O I：
暂无
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学科分类号：
摘要：
The X-ray crystal structure of 1-(4-fluorophenyl)-and 1-(4-dimethylaminophenyl)germatranes reveals that the germanium atom is pentacoordinated and adopts a trigonal bipyramidal geometry. The fluorophenyl and dimethylaminophenyl groups and the nitrogen atom each occupy an apical position with the transannular N→Ge bond of 2.192(3) and 2.249(3) Å; the deviation of the Ge atom from the O(2)-O(8)-O(9) plane is 0.2306(4) and 0.2693(3) Å, correspondingly.
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页码：615 / 620
页数：5
相关论文
共 41 条
[1]  
Karlov E. S.(2001)undefined Khim. Geterotsikl Soed. 37 1451-undefined
[2]  
Zaitseva G. S.(2006)undefined Acta Crystallogr. 62C 303-undefined
[3]  
Korlyukov A. A.(2004)undefined Organometallics 23 3184-undefined
[4]  
Komissarov E. A.(1999)undefined J. Organomet. Chem. 588 222-undefined
[5]  
Alekseev N. V.(1984)undefined Zh. Obshch. Khim. 54 2590-undefined
[6]  
Pavlov K. V.(1999)undefined J.Organomet.Chem. 577 205-undefined
[7]  
Krivolapova O. V.(2003)undefined Main Group Met. Chem. 26 67-undefined
[8]  
Lachtin V. G.(2002)undefined Main Group Met. Chem. 25 313-undefined
[9]  
Kultyshev R. G.(2005)undefined Appl. Organomet. Chem. 19 167-undefined
[10]  
Prakash G. K. S.(1994)undefined J. Appl. Cryst. 27 435-undefined
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