Syntheses, Crystal Structures and Physical Properties of Four Zinc/Cadmium Coordination Polymers Based on 4-Nitrophthalic Acid and N-donor Auxiliary Ligands

被引:0
作者
Peng-Fei Wang
Shang Wu
Suyang He
Yangyang Wang
机构
[1] Chizhou College,Department of Materials and Chemical Engineering
来源
Journal of Inorganic and Organometallic Polymers and Materials | 2014年 / 24卷
关键词
Coordination polymer; Multicarboxylate; Luminescence;
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摘要
Four new d10 metal coordination polymers, [Zn(4-NPA)(2,2-bipy)]n (1), [Zn(4-NPA)(1,3-bimb)·H2O]n (2), [Cd(4-NPA)(2,2-bipy)]n (3) and [Cd(4-NPA)(1,3-bimb)·H2O]n (4) (4-NPAH2 = 4-nitrophthalic acid, 2,2-bipy = 2,2-bipyridine, 1,3-bimb = 1,3-bis(imidazol-1-ylmethyl)-benzene), have been hydrothermally synthesized and characterized by elemental analyses, IR spectra, and X-ray single crystal diffractions. Compounds 1−3 possess different one-dimensional (1D) chain structures. Compound 4 shows a two-dimensional (2D) layered structure. Moreover, the luminescent and thermal stabilities properties of compounds 1–4 were investigated in the solid state.
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页码:608 / 616
页数:8
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