Electrochemiluminescent detection of labile radical intermediates of electrochemical reactions

被引：0
|
作者：
Olena M. Bilash
Yuriy T. Zholudov
Mykola M. Rozhitskii
机构：
[1] Kharkiv National University of Radio Electronics,Laboratory of Analytical Optochemotronics
来源：
Journal of Solid State Electrochemistry | 2011年 / 15卷
关键词：
Electrogenerated chemiluminescence; Free radicals; Mechanistic investigation; Assay;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The article considers the basic principles of electrochemiluminescent spin traps diagnostic method which consists of efficient trapping of intermediate labile radical products (free radicals of complex organic molecules) by electrogenerated radical ions of electrochemiluminescers in different liquid-phase systems including bioobjects. The method permits qualitative and quantitative identification of such particles by measurement of electrolysis radical recombination luminescence (electrogenerated chemiluminescence) intensity which is emitted by electrolyzed solutions of organic electrochemiluminescers. The unique possibilities of the method are illustrated on examples of experimental study of systems with sodium tetraphenylborate and chloride ion.
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页码：2127 / 2131
页数：4
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