Thermodynamics of mixed-ligand complexation of gadolinium ethylenediaminetetraacetate with amino acids in aqueous solution

被引：0

作者：

T. S. Krivonogikh

D. F. Pyreu

E. V. Kozlovskii

机构：

[1] Ivanovo State University,

来源：

Russian Journal of Coordination Chemistry | 2010年 / 36卷

关键词：

Coordination Chemistry; Carboxy Group; Acetate Group; Additional Ligand; Iminodiac Etate;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Mixed-ligand complexation of GdEdta− with glycinate, L-glutamate, DL-aspartate, iminodiacetate, and nitrilotriacetate anions in aqueous solutions at 298.15 K and the ionic strength I = 0.5 (KNO3) was studied. The thermodynamic parameters (logK, ΔrG, ΔrH, ΔrS) of these reactions were determined from calorimetric and pH-metric data. The most probable way of coordination of the amino acids in the heteroleptic complexes is discussed.

引用

页码：552 / 557

页数：5

共 50 条

[31] EQUILIBRIUM STUDIES OF MIXED-LIGAND COMPLEXES OF URANYL-ION WITH AMINO-ACIDS AND CARBOXYLIC-ACIDS IN AQUEOUS-SOLUTION
SELVARAJ, PV
SANTAPPA, M
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1977, 39 (01): : 119 - 122
[32] FORMATION OF MIXED-LIGAND COMPLEXES OF COPPER(II) WITH AROMATIC HYDROXY-ACIDS AND ALPHA-AMINO-ACIDS IN AQUEOUS-SOLUTION
MIGAL, PK
GERBELEU, AP
KALITINA, PG
UTKINA, TK
ZHURNAL NEORGANICHESKOI KHIMII, 1978, 23 (06): : 1593 - 1601
[33] Formation of Mixed-Ligand Complexes of Metals(II) with Monoamine Complexones and Amino Acids in Solution
D. F. Pyreu
S. N. Gridchin
Russian Journal of Physical Chemistry A, 2018, 92 : 909 - 917
[34] Formation of Mixed-Ligand Complexes of Metals(II) with Monoamine Complexones and Amino Acids in Solution
Pyreu, D. F.
Gridchin, S. N.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2018, 92 (05) : 909 - 917
[35] Thermodynamics of Mixed-Ligand Complexation of Copper(II) with Triglycine and L-Histidine
Gorboletova, G. G.
Bychkova, S. A.
Frolova, K. O.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2019, 93 (07) : 1225 - 1229
[36] THERMODYNAMICS OF ZINC CARBOXYLATE MIXED-LIGAND COMPLEXATION WITH 1,10-PHENANTHROLINE
KOZLOV, SK
PYARTMAN, AK
ZHURNAL OBSHCHEI KHIMII, 1990, 60 (06): : 1314 - 1317
[37] Thermodynamics of Mixed-Ligand Complexation of Copper(II) with Triglycine and L-Histidine
G. G. Gorboletova
S. A. Bychkova
K. O. Frolova
Russian Journal of Physical Chemistry A, 2019, 93 : 1225 - 1229
[38] Thermodynamic Parameters of the Mixed-Ligand Complexation of Cobalt(II) with Triglycine and L-Histidine in an Aqueous Solution
G. G. Gorboletova
S. A. Bychkova
E. A. Gorbashova
K. O. Frolova
Russian Journal of Physical Chemistry A, 2020, 94 : 1816 - 1821
[39] Thermodynamic Parameters of the Mixed-Ligand Complexation of Cobalt(II) with Triglycine and L-Histidine in an Aqueous Solution
Gorboletova, G. G.
Bychkova, S. A.
Gorbashova, E. A.
Frolova, K. O.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2020, 94 (09) : 1816 - 1821
[40] Recovery of amino acids from aqueous solution by reversible complexation with mixed organic extractants
Cameron, T
Husson, SM
SEPARATION SCIENCE AND TECHNOLOGY, 2001, 36 (5-6) : 849 - 866

← 1 2 3 4 5 →