The crystal structure of a bis(2,6-pyridinedicarboxylato)chromate(III) anion with an elaborate network of hydrogen bonding and π stacking

被引：0

作者：

Vince C. R. Payne

Oliver St. C. Headley

Robert T. Stibrany

Paul T. Maragh

Tara P. Dasgupta

Anthony M. Newton

Alvin A. Holder

机构：

[1] University of the West Indies,Department of Biological and Chemical Sciences

[2] The State University of New Jersey,Department of Chemistry and Chemical Biology, Rutgers

[3] University of the West Indies,Department of Chemistry

[4] The University of Southern Mississippi,Department of Chemistry and Biochemistry

来源：

Journal of Chemical Crystallography | 2007年 / 37卷

关键词：

chromium(III); 2,6-pyridinedicarboxylic acid (dipicolinic acid); hydrogen bonding; π-stacking; X-ray; infrared; electrochemistry;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The synthesis, X-ray crystallography, spectroscopic, and electrochemical properties of the title compound, [Hdpa][Cr(dipic)2]·3H2O, 1, are reported. Compound 1 crystallized in the triclinic space group P-1 with a = 7.1057(11) Å, b = 12.965(2) Å, c = 14.269(2) Å, α = 80.306(3)°, β = 82.101(2)°, γ = 83.799(2)°, and V = 1278.6(4) Å3 with Z = 2. The distorted octahedral chromium anions are part of an elaborate network of hydrogen bonding formed by the waters of solvation, the anion, and cation as well as π-stacking interactions.

引用

页码：309 / 314

页数：5

共 16 条

[1] The crystal structure of a bis(2,6-pyridinedicarboxylato)chromate(III) anion with an elaborate network of hydrogen bonding and π stacking
Payne, Vince C. R.
Headley, Oliver St C.
Stibrany, Robert T.
Maragh, Paul T.
Dasgupta, Tara P.
Newton, Anthony M.
Holder, Alvin A.
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2007, 37 (04) : 309 - 314
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