Solvent Effects on the Solubility of C60 fullerene

被引:0
作者
R. G. Makitra
R. E. Pristanskii
R. I. Flyunt
机构
[1] National Academy of Sciences of Ukraine,Division of Physical Chemistry and Technology of Fossil Fuels, Pisarzhevskii Institute of Physical Chemistry
来源
Russian Journal of General Chemistry | 2003年 / 73卷
关键词
Energy Density; Fullerene; Solvent Polarity; Solvent Effect; Cohesive Energy;
D O I
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中图分类号
学科分类号
摘要
The solubility of C60 fullerene in organic liquids is not directly related to any of their physicohemical characteristics, but can be quantitatively described by linear multiparameter equations. The solubility increases with increasing solvent polarizability and decreases with increasing solvent polarity and cohesive energy density. Various types of multiparameter equations proposed in the literature were compared to show that they all are suitable but Koppel-Palm's equation is preferred.
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页码:1227 / 1232
页数:5
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共 40 条
  • [1] Sivaraman N.(1992)undefined J. Org. Chem. 57 6077-undefined
  • [2] Dhamodaran R.(1993)undefined Chem. Commun. 10 1207-undefined
  • [3] Kaliappan I.(1993)undefined J. Phys. Chem. 97 3379-undefined
  • [4] Srinivasan T.G.(1987)undefined Monatsh. Chem. 109 421-undefined
  • [5] Vasudeva Rao P.R.(1987)undefined Reakts. Sposobn. Org. Soedin. 24 30-undefined
  • [6] Mathews C.K.(1993)undefined Zh. Prikl. Khim. 66 2038-undefined
  • [7] Scrivens V.A.(1997)undefined Org. React. 31 21-undefined
  • [8] Tour J.M.(1997)undefined J. Phys. Chem. B 101 8617-undefined
  • [9] Ruoff R.F.(2000)undefined J. Phys. Chem. A 104 8081-undefined
  • [10] Tse D.S.(1977)undefined J. Am. Chem. Soc. 99 6027-undefined