Phosphorylation of Pyrimidinophane in the Reversed Micellar Solutions of Cationic and Nonionogenic Surfactants

被引：0
|
作者：
E. P. Zhil'tsova
L. A. Kudryavtseva
G. A. Gainanova
A. P. Timosheva
A. S. Mikhailov
R. H. Giniyatullin
A. A. Nafikova
V. S. Reznik
A. I. Konovalov
机构：
[1] Russian Academy of Sciences,Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
来源：
Russian Journal of General Chemistry | 2005年 / 75卷
关键词：
Surfactant; Bromide; Chloroform; Catalytic Activity; Molar Fraction;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Reactions of a macrocycle containing three pyrimidine fragments and N,N′-bis(2-methylthio-6-methylpyrimidin-4-yl)-hexamethylenediamine with p-nitrophenyl bis(chloromethyl)phosphinate in the micellar solutions of cetyltrimethylammonium bromide, polyethyleneglycol-600 laurate and their mixture in chloroform was investigated spectrophotometrically. Catalytic activity of micelles depends on their structure, concentration of surfactants, molar fraction of the latter in solution, and structure of the nucleophilic reagent.
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页码：1729 / 1734
页数：5
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