Kinetic isotope H/D effect in the oxidation of ethers of linoleic acid in solutions

被引：0
作者：
I. V. Tikhonov
I. V. Moskalenko
E. M. Pliss
M. A. Fomich
A. V. Bekish
V. V. Shmanai
机构：
[1] Demidov Yaroslavl University,Institute of Physical Organic Chemistry
[2] National Academy of Sciences of Belarus,undefined
[3] Belarus State University,undefined
来源：
Russian Journal of Physical Chemistry B | 2017年 / 11卷
关键词：
kinetic isotope effect; oxidation; polyunsaturated fatty acids; hydrogen atom abstraction;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
It is shown that the initiated oxidation of deuterated esters of linoleic acid proceeds as a radical chain process. The value of the kinetic isotope effect for hydrogen atom abstraction from the bisallyl group of linoleic acid esters is determined: 3.0 for tert-butyl peroxy and cumylperoxy radicals.
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页码：395 / 399
页数：4
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