Kinetic isotope H/D effect in the oxidation of ethers of linoleic acid in solutions

被引:0
作者
I. V. Tikhonov
I. V. Moskalenko
E. M. Pliss
M. A. Fomich
A. V. Bekish
V. V. Shmanai
机构
[1] Demidov Yaroslavl University,Institute of Physical Organic Chemistry
[2] National Academy of Sciences of Belarus,undefined
[3] Belarus State University,undefined
来源
Russian Journal of Physical Chemistry B | 2017年 / 11卷
关键词
kinetic isotope effect; oxidation; polyunsaturated fatty acids; hydrogen atom abstraction;
D O I
暂无
中图分类号
学科分类号
摘要
It is shown that the initiated oxidation of deuterated esters of linoleic acid proceeds as a radical chain process. The value of the kinetic isotope effect for hydrogen atom abstraction from the bisallyl group of linoleic acid esters is determined: 3.0 for tert-butyl peroxy and cumylperoxy radicals.
引用
收藏
页码:395 / 399
页数:4
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