Palladium-catalyzed acyldemetallation of organomercurials in aqueous media

被引：0
作者：
E. V. Luzikova
N. A. Bumagin
机构：
[1] M. V. Lomonosov Moscow State University,Deparment of Chemistry
来源：
Russian Chemical Bulletin | 1997年 / 46卷
关键词：
organomercurials; acyl chlorides; acyldemercuration; ketones; palladium; catalysis; aqueous medium;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Palladium- and iodide ion-catalyzed acyldemercuration of R2Hg(RHgI) by aroyl chlorides (ArCOCI) can be carried out in aqueous media. Nonsymmetrical ketones (ArCOR) are obtained in high yields along wiht oxidative demercuration products (R2) in trace quantities. The possible reaction mechanism and the role of the iodide ion are discussed.
引用
收藏
页码：1961 / 1962
页数：1
相关论文
共 17 条
  • [1] Skoldinov A. P.(1942)undefined Zh. Obshch. Khim. 12 398-398
  • [2] Kocheshkov K. A.(1969)undefined J. Organomet. Chem. 17 21-21
  • [3] Kurtz A. L.(1978)undefined J. Org. Chem. 43 710-710
  • [4] Beletskaya I. P.(1984)undefined Izv. Akad. Nauk SSSR, Ser. Khim. 33 2347-379
  • [5] Savchenko I. P.(1989)undefined J. Organomet. Chem. 365 379-951
  • [6] Reutov O. A.(1975)undefined J. Am. Chem. Soc. 97 951-1117
  • [7] Larock R. C.(1928)undefined Zh. Ross. Fiz.-Khim. Ob-va 60 1117-undefined
  • [8] Bernhardt J. C.(undefined)undefined undefined undefined undefined-undefined
  • [9] Burnagin N. A.(undefined)undefined undefined undefined undefined-undefined
  • [10] Kalinovskii I.O.(undefined)undefined undefined undefined undefined-undefined
12