13C-13C Spin-Spin Coupling Constants in Structural Studies: XXXI. Bicyclo[2.1.0]pentane Heteroanalogs

被引：0
作者：
T. A. Kuznetsova
N. V. Istomina
L. B. Krivdin
机构：
[1] Angarsk State Institute of Technology,
来源：
Russian Journal of Organic Chemistry | 2002年 / 38卷
关键词：
Organic Chemistry; Perturbation Theory; Pentane; Structural Study; Orbital Hybridization;
D O I：
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学科分类号：
摘要：
13C-13C spin-spin coupling constants and orbital hybridization of the bridging bond in bicyclo[2.1.0]pentane heteroanalogs and their unsaturated derivatives were calculated in terms of the self-consistent finite perturbation theory (SCPT INDO). The results showed that the bridging CÄC bond in all the examined compounds has an anomaloulsy low s character.
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页码：394 / 398
页数：4
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