Effect of central metal ions on interaction of Metal Phthalocyanines composites with chemical analytes

被引：0

作者：

Ridhi, R. ^{[1
,2
]}

Saini, G. S. S. ^{[1
]}

Tripathi, S. K. ^{[1
]}

机构：

[1] Panjab Univ, Dept Phys, Chandigarh 160014, India

[2] Mehr Chand Mahajan DAV Coll Women, Sect 36, Chandigarh 160036, India

来源：

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING | 2024年 / 130卷 / 05期

关键词：

Chemical vapors; Benzene; Bromine; Dispersed glasses; Metal Phthalocyanines; Chemresistors; COPPER PHTHALOCYANINE; ORGANIC VAPORS; FILMS;

D O I：

10.1007/s00339-024-07502-x

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Metal Phthalocyanines (MPcs) undergo appreciable interaction mechanism with chemical analytes on account of their high sensitivity in terms of charge densities, optical and spectroscopic properties. In the present work, we aim to integrate the advantages of three MPcs with three different metal ions, similar functional group and a ligand attached to central metal ion to device chemresistor sensors. Four chemresistor devices were fabricated using permutation combinations of three MPcs; tetrasulfonic acid tetrasodium salt functionalized Nickel Phthalocyanine (NiPcS) and Copper Phtalocyanines (CuPcS) and Aluminium Phthalocyanine hydroxide (AlPcOH). The chemresistors were tested for surface-interface studies with an aromatic vapor benzene and strong oxidizing vapor bromine. For benzene, NiPcS-AlPcOH composite exhibited maximum sensitivity (approximate to 2.73 ppm-1) and for bromine, CuPcS-AlPcOH composite shows highest sensitivity (approximate to 72 ppm-1).

引用

页数：17

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