Five-membered 2,3-dioxoheterocycles: CVIII. [3+3]-Nucleophilic addition of acyclic enaminoketones to 4,5-dimethoxycarbonyl-1H-pyrrole-2,3-diones. Crystal and molecular structure of substituted 2,6-diazabicyclo[3.2.1]oct-3-enes

被引:0
作者
P. S. Silaichev
M. A. Zheleznova
P. A. Slepukhin
A. N. Maslivets
机构
[1] Perm State National Research University,Postovskii Institute of Organic Synthesis, Ural Branch
[2] Russian Academy of Sciences,undefined
来源
Russian Journal of Organic Chemistry | 2014年 / 50卷
关键词
Diones; Dicarboxylates; Nucleophilic Addition; Polar Contact; Anhydrous Benzene;
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摘要
1-Aryl-4,5-dimethoxycarbonyl-1H-pyrrole-2,3-diones react with 4-aminopent-3-en-2-one and 3-amino-1-phenylbut-2-en-1-one affording dimethyl 4-acyl-1-hydroxy-3-methyl-7-oxo-6-(4-chlorophenyl)-2,6-diazabicyclo[3.2.1]oct-3-ene-5,8-dicarboxylates whose structure was proved by X-ray diffraction analysis.
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页码:1594 / 1597
页数:3
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