Determination of glass transitions and PMMA/Al2O3 by thermal and chromatographic methods [Determination des transitions vitreuses et locales de PMMA/Al2O3 par des methodes thermiques et chromatographiques]

被引:0
|
作者
Hamieh T. [1 ]
Rezzaki M. [1 ]
Schultz J. [1 ]
机构
[1] Inst de Chimie des Surfaces et, Interfaces (ICSI-CNRS), Mulhouse
关键词
adsorption; alumina; glass transition; inverse gas chromatography; PMMA; thermal analysis;
D O I
10.1007/BF03341456
中图分类号
学科分类号
摘要
Differential thermal analysis (DTA) technique was used to determine the glass transition temperatures of polymethyl methacrylate (PMMA). When PMMA was adsorbed on α-alumina, DTA could not use to obtain the glass transition temperatures of the system PMMA/α-Al2O3. Inverse gas chromatography at infinite dilution proved to be an excellent technique to highlight glass transitions and local transitions of PMMA adsorbed on α-Al2O3, at various covered surface fractions.
引用
收藏
页码:793 / 804
页数:11
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