Oxidation of Cyclohexene in the Presence of Alkanes in a Barrier Discharge Plasma

被引：0
作者：
S. V. Kudryashov
A. Yu. Ryabov
E. E. Sirotkina
G. S. Shchegoleva
机构：
[1] Institute of Petroleum Chemistry,Siberian Division, Russian Academy of Sciences
来源：
High Energy Chemistry | 2003年 / 37卷
关键词：
Oxidation; Physical Chemistry; Hexane; Alkane; Partial Pressure;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The oxidation of cyclohexene mixtures with hexane, octane, decane, and cyclohexane was studied in a dielectric-barrier discharge reactor. It was shown that a decrease in the partial pressure of cyclohexene in the mixture resulted in a significant increase in the yield of cyclohexene oxide to ∼75%, with the composition of oxidation products being the same as in the oxidation of individual compounds. A plausible mechanism of the reaction is proposed.
引用
收藏
页码：184 / 186
页数：2
相关论文
共 50 条
[1]   Oxidation of cyclohexene in the presence of alkanes in a barrier discharge plasma [J].
Kudryashov, SV ;
Ryabov, AY ;
Sirotkina, EE ;
Shchegoleva, GS .
HIGH ENERGY CHEMISTRY, 2003, 37 (03) :184-186
[2]   Combined Oxidation of Gaseous and Liquid Alkanes in the Barrier Discharge Plasma [J].
Ryabov, A. Yu. ;
V. Kudryashov, S. ;
Ocheredko, N. .
CHEMISTRY FOR SUSTAINABLE DEVELOPMENT, 2024, 32 (01) :190-195
[3]   Oxidation of Propylene with Oxygen and Air in a Barrier Discharge in the Presence of Octane [J].
Sergey Kudryashov ;
Andrey Ochered’ko ;
Andrey Ryabov ;
Galina Shchyogoleva .
Plasma Chemistry and Plasma Processing, 2011, 31 :649-661
[4]   Oxidation of Propylene with Oxygen and Air in a Barrier Discharge in the Presence of Octane [J].
Kudryashov, Sergey ;
Ochered'ko, Andrey ;
Ryabov, Andrey ;
Shchyogoleva, Galina .
PLASMA CHEMISTRY AND PLASMA PROCESSING, 2011, 31 (05) :649-661
[5]   Oxidative Conversion of Gaseous Alkanes C3-C4 in the Barrier Discharge Plasma [J].
Kudryashov, Sergey, V ;
Ryabov, Andrey Yu ;
Ocheredko, Andrey N. .
JOURNAL OF SIBERIAN FEDERAL UNIVERSITY-CHEMISTRY, 2019, 12 (01) :126-135
[6]   Oxidation of cumene and its mixture with benzene by oxygen in the dielectric barrier discharge plasma [J].
Ochered'ko, A. N. ;
Leshchik, A. V. ;
Ryabov, A. yU. ;
Kudryashov, S. V. .
CHEMISTRY FOR SUSTAINABLE DEVELOPMENT, 2025, 33 (02) :214-218
[7]   Simulation of the Kinetics of Cyclohexane Oxidation in a Barrier Discharge Reactor [J].
S. V. Kudryashov ;
G. S. Shchegoleva ;
A. Yu. Ryabov ;
E. E. Sirotkina .
High Energy Chemistry, 2002, 36 :349-354
[8]   OXIDATION OF PROPANE-BUTANE MIXTURE IN DIELECTRIC BARRIER DISCHARGE IN PRESENCE OF LIQUID OCTANE [J].
Kudryashov, S. V. ;
Ryabov, A. Yu. ;
Ocheredko, A. N. .
IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA, 2018, 61 (03) :88-92
[9]   BIOMIMETIC OXIDATION OF ALKANES [J].
Karasevich, E. I. .
OXIDATION COMMUNICATIONS, 2010, 33 (04) :741-781
[10]   OXIDATION OF ALKYLAROMATICS BY OXYGEN IN THE DIELECTRIC BARRIER DISCHARGE [J].
Leshchik, A. V. ;
Ochered'ko, A. N. ;
Ryabov, A. Yu. ;
Kudryashov, S. V. .
IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA, 2024, 67 (08) :15-21
12345