Using Porous Ceramic Catalytic Converters for Dehydrogenation of Propane in Propylene
被引:0
作者:
V. I. Uvarov
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机构:Russian Academy of Sciences (MISMMS RAN),A. G. Merzhanov Institute of Structural Macrokinetics and Materials Science
V. I. Uvarov
V. É. Loryan
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机构:Russian Academy of Sciences (MISMMS RAN),A. G. Merzhanov Institute of Structural Macrokinetics and Materials Science
V. É. Loryan
R. D. Kapustin
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机构:Russian Academy of Sciences (MISMMS RAN),A. G. Merzhanov Institute of Structural Macrokinetics and Materials Science
R. D. Kapustin
A. S. Fedotov
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机构:Russian Academy of Sciences (MISMMS RAN),A. G. Merzhanov Institute of Structural Macrokinetics and Materials Science
A. S. Fedotov
M. V. Tsodikov
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机构:Russian Academy of Sciences (MISMMS RAN),A. G. Merzhanov Institute of Structural Macrokinetics and Materials Science
M. V. Tsodikov
G. I. Konstantinov
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机构:Russian Academy of Sciences (MISMMS RAN),A. G. Merzhanov Institute of Structural Macrokinetics and Materials Science
G. I. Konstantinov
机构:
[1] Russian Academy of Sciences (MISMMS RAN),A. G. Merzhanov Institute of Structural Macrokinetics and Materials Science
[2] Russian Academy of Sciences (TIPS RAN),A. V. Topchiev Institute of Petrochemical Synthesis
来源:
Glass and Ceramics
|
2020年
/
76卷
关键词:
cermet membrane;
self-propagating high temperature synthesis (SHS);
ceramic;
catalytic converter;
propylene;
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学科分类号:
摘要:
Self-propagating high temperature synthesis (SHS) was used to obtain porous cermet membranes based on a mixture of aluminum oxide, silicon carbide, and magnesium oxide powders. The obtained membranes are catalytically active. The surfaces of the open pores in them were modified by rhenium-tungsten active components using the alkoxy method. The highest selectivity in terms of propane (about 60%) is achieved at temperature 600°C. In addition, the optimal conditions for implementing the propane dehydrogenation process is temperature 650°C at which the quite high selectivity for the most important monomers remains with a relatively small contribution of accessory processes.