Preparation and characterization of perfluorosulfonic resin/titania hybrid transparent films

被引:0
作者
JianMei Li
MinZhao Xue
YongMing Zhang
YanGang Liu
机构
[1] Shanghai Jiaotong University,College of Chemistry and Chemical Engineering
来源
Science in China Series B: Chemistry | 2007年 / 50卷
关键词
perfluorosulfonic resin; hybrid; titania;
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中图分类号
学科分类号
摘要
Preparation and characterization of perfluorosulfonic resin/titania organic-inorganic hybrid films were presented. The transparent hybrid films were prepared by hydrothermal treatment at low temperature of a mixed solution of tetrabutyl titanate and perfluorosulfonic resin with the help of acetylacetone. The characterization was carried out by SEM, XRD, FT-IR, UV-Vis and TGA. The results showed that the perfluorosulfonic resin/titania hybrid transparent films were composed of titania particles dispersed in the perfluorosulfonic resin matrix very well and the titania was of anatase phase. Its diameter decreased with increasing weight ratio of titania to perfluorosulfonic resin.
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页码:243 / 248
页数:5
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[1]  
Siuzdak A.(2003)Surlyn/titanate hybrid materials via polymer in situ sol-gel chemistry J Polym Sci B: Polym Phys 41 11-22
[2]  
Start R.(1998)Organic-inorganic hybrid materials: Perfluorinated ionomer as sol-gel polymerization templates for inorganic alkoxides Mater Sci Eng C 6 121-133
[3]  
Mauritz A.(1993)Structure and morphology of sol-gel prepared polymer-ceramic composite thin films Polymer 34 4607-4612
[4]  
Mauritz A.(2005)Fabrication of an organic-inorganic hybrid LB film of a magnetic polyoxometalate Syn Matals 153 469-472
[5]  
Embs W. F.(1999)A new catalytic hybrid material from simple acid-base hydrolytic chemistry J Mol Catal A: Chem 146 309-315
[6]  
Wung L. J.(1999)Sol-gel derived hybrid inorganic-organic nanacomposites for optics Curr Opin Solid St M Sci 4 11-23
[7]  
Prasad N.(2003)Inorganic-organic hybrid materials for application in optical devices Thin Solid Films 442 194-200
[8]  
Kim H. S.(2001)Solid acid catalysis using ion-exchange resins Appl Catal A-Gen 221 45-62
[9]  
Lee B. J.(1985)Integrated chemical system: Photocatalysis at TiO J Phy Chem 89 4418-4420
[10]  
Prak D. H.(2005) incorporated into nafion and clay Langmuir 21 172-177