Nanoparticles based on gadolinium(iii) and europium(iii) complexes for biovisualization

被引:0
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作者
R. R. Zairov
N. А. Shamsutdinova
А. N. Fattakhova
А. V. Pyataev
А. F. Abdullin
А. V. Gerasimov
А. Т. Gubaidullin
А. R. Mustafina
机构
[1] Kazan Scientific Center of the Russian Academy of Sciences,A. E. Arbuzov Institute of Organic and Physical Chemistry
[2] Kazan (Volga Region) Federal University,undefined
来源
Russian Chemical Bulletin | 2016年 / 65卷
关键词
lanthanide(; ) complexes; polyelectrolyte nanoparticles; human blood serum; Eu; Mössbauer spectroscopy;
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摘要
Complexes Ln(TTA)3 and [Ln(TTA)3·1] (Ln = Eu, Gd; ТТА is thenoyltrifluoroacetyl-acetonate; 1 is 2-(5-chlorophenylene-2-hydroxy)-2-phenylethylene-bis(2-methoxy)phosphine oxide) in individual form, and as a part of a core of the polyelectrolyte stabilized colloids have been studied by Mössbauer spectroscopy and X-ray powder diffraction. The photophysical and colloidal characteristics of the solutions of polyelectrolyte nanoparticles were studied in water, artificial cerebrospinal fluid solution, solution of bovine serum albumin, and human blood serum. A stability of a luminescent response of the nanoparticles in solutions of bovine serum albumin and human blood serum at 37 °С for 2 hours has been revealed. This is a prerequisite for the potential application of studied nanoparticles for biovisualization.
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页码:1325 / 1331
页数:6
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