Transport properties of alkali fluoride high temperature ionic liquids and application of theories of viscous flow

被引：0
|
作者：
Anamaria Popescu
Virgil Constantin
机构：
[1] Romanian Academy,Laboratory of Molten Salts, “Ilie Murgulescu” Institute of Physical Chemistry
[2] Technology Transfer Center(CTT-ICF),undefined
来源：
Chemical Research in Chinese Universities | 2015年 / 31卷
关键词：
Ionic liquid; Alkali fluoride; Viscosity; Temperature dependence; Correlation; Fluidity;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The transport properties of several alkali fluoride high temperature ionic liquids(LiF, NaF, KF, RbF and CsF) were studied in a range of 980―1400 K and the temperature dependences of the viscosity and density were interpreted, in agreement with the classical equations characterizing the viscous flow(Arrhenius, Batchinski, Eyring and Frenkel). The experimental results reveal the validity of these equations even at high temperatures, suggesting that no significant structural changes of alkali fluorides occurred in the studied temperature range. Our results clearly demonstrate that the mentioned thermo-physical properties can be used as powerful tools in the further investigations of the ionic interactions governing the alkali fluoride molten salts.
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页码：858 / 864
页数：6
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