Photocatalytic reactions of fluoroalkyl iodides with alkenes

被引：0
作者：
G. I. Chernov
V. V. Levin
A. D. Dilman
机构：
[1] Tomsk Polytechnic University,Research School of Chemistry and Applied Biomedical Sciences
[2] Russian Academy of Scienses,N. D. Zelinsky Institute of Organic Chemistry
来源：
Russian Chemical Bulletin | 2023年 / 72卷
关键词：
organofluorine chemistry; fluoroalkyl iodides; alkenes; photocatalysis; radicals;
D O I：
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中图分类号：
学科分类号：
摘要：
Fluoroalkyl iodides are convenient sources of fluoroalkyl radicals under photocatalytic conditions. After the addition of a fluorine radical to a double bond, the resulting radical can react in several directions, including abstraction of an iodine atom from the starting iodide, abstraction of a hydrogen atom from a reducing agent, intramolecular interception by an aromatic system, and one-electron oxidation. These reactions make it possible to obtain a wide range of organofluorine compounds. The review summarizes data for the last five years.
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页码：61 / 72
页数：11
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