Photocatalytic reactions of fluoroalkyl iodides with alkenes

被引：0
作者：
G. I. Chernov
V. V. Levin
A. D. Dilman
机构：
[1] Tomsk Polytechnic University,Research School of Chemistry and Applied Biomedical Sciences
[2] Russian Academy of Scienses,N. D. Zelinsky Institute of Organic Chemistry
来源：
Russian Chemical Bulletin | 2023年 / 72卷
关键词：
organofluorine chemistry; fluoroalkyl iodides; alkenes; photocatalysis; radicals;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Fluoroalkyl iodides are convenient sources of fluoroalkyl radicals under photocatalytic conditions. After the addition of a fluorine radical to a double bond, the resulting radical can react in several directions, including abstraction of an iodine atom from the starting iodide, abstraction of a hydrogen atom from a reducing agent, intramolecular interception by an aromatic system, and one-electron oxidation. These reactions make it possible to obtain a wide range of organofluorine compounds. The review summarizes data for the last five years.
引用
收藏
页码：61 / 72
页数：11
相关论文
共 226 条
[1]  
Inoue M(2022)undefined Russ. Chem. Bull. 71 1559-10640
[2]  
Sumii Y(2020)undefined ACS Omega 5 10633-5880
[3]  
Shibata N(2018)undefined J. Med. Chem. 61 5822-6386
[4]  
Meanwell N A(2020)undefined J. Fluorine Chem. 239 109639-67
[5]  
Han J(2020)undefined J. Med. Chem. 63 6315-7307
[6]  
Remete A M(2022)undefined Russ. Chem. Bull. 71 1-2294
[7]  
Dobson L S(2020)undefined iScience 23 101467-1584
[8]  
Kiss L(2021)undefined Chimia 75 923-6926
[9]  
Izawa K(2016)undefined J. Fluorine Chem. 189 59-1577
[10]  
Moriwaki H(2018)undefined ACS Catal. 8 7287-1622
12345678910