Mixed-ligand complexes of tris(acetylacetonato)iridium(III) with N-heterocyclic ligands: synthesis and crystal structure

被引：0

作者：

Qiaowen Chang

Changyi Hu

Jialin Chen

Mingjin Xie

Weiping Liu

Qingsong Ye

Yao Yu

Xizhu Chen

Liqiao Chen

机构：

[1] Kunming Institute of Precious Metals,State Key Lab of Advanced Technologies of PGM

[2] Yunnan University,Department of Chemistry

来源：

Transition Metal Chemistry | 2011年 / 36卷

关键词：

Tris(acetylacetonato)iridium; Crystal structure; -heterocyclic ligands; Picoline;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

A series of mixed-ligand complexes of tris(acetylacetonato) iridium(III) with N-heterocyclic ligands, namely [bis(acac-O,O′)(acac-C3)Ir(L)], where acac = acetyacetonato; L = 2-picoline (1), 3-picoline (2), 4-picoline (3), have been synthesized via the reaction of [bis(acac-O,O′) (acac-C3)Ir(H2O)] with the corresponding ligand, respectively. Molecular structures of all complexes were determined by using single-crystal X-ray diffraction. The results reveal that these complexes have slightly distorted octahedral coordination geometries.

引用

页码：337 / 340

页数：3

共 50 条

[31] SOME MIXED-LIGAND MANGANESE(III) COMPLEXES PRODUCED BY REACTIONS OF "TRIS(ACETYLACETONATO)MANGANESE(III) WITH HYDROGEN HALIDES IN ORGANIC-SOLVENTS
ISOBE, K
KAWAGUCHI, S
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1975, 48 (01) : 250 - 257
[32] SOME MIXED-LIGAND IRON(III) COMPLEXES PRODUCED BY REACTIONS OF TRIS(ACETYLACETONATO)IRON(III) WITH HYDROGEN HALIDES IN ORGANIC-SOLVENTS
TAKEDA, K
ISOBE, K
NAKAMURA, Y
KAWAGUCHI, S
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1976, 49 (04) : 1010 - 1016
[33] Reactivity of tris(acetylacetonato) iron(III) with tridentate [ONO] donor Schiff base as an access to newer mixed-ligand iron(III) complexes
Bhattacharjee, Chira R.
Goswami, Pankaj
Pramanik, Harun A. R.
Paul, Pradip C.
Mondal, Paritosh
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2011, 78 (05) : 1408 - 1415
[34] Tuning the electrochemiluminescent properties of iridium complexes of N-heterocyclic carbene ligands
Quan, Linh M.
Stringer, Bradley D.
Haghighatbin, Mohammad A.
Agugiaro, Johnny
Barbante, Gregory J.
Wilson, David J. D.
Hogan, Conor F.
Barnard, Peter J.
DALTON TRANSACTIONS, 2019, 48 (02) : 653 - 663
[35] SYNTHESIS, STRUCTURE, AND PROPERTIES OF REE MIXED-LIGAND COMPLEXES CONTAINING DIPIVALOYLMETHANATE AND PIVALATE LIGANDS - MIXED-LIGAND COMPLEXES OF HOLMIUM, ERBIUM, AND YTTERBIUM
KUZMINA, NP
TU, ZA
PISAREVSKII, AP
MARTYNENKO, LI
STRUCHKOV, YT
KOORDINATSIONNAYA KHIMIYA, 1994, 20 (8-9): : 707 - 711
[36] Heteroleptic and Homoleptic Iron(III) Complexes with a Tris(N-Heterocyclic Carbene) Borate Ligand: Synthesis, Characterization, and Catalytic Application
Sato, Yuna
Okamura, Masaya
Hikichi, Shiro
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2023, 26 (14)
[37] MIXED-LIGAND COMPLEXES OF COBALT(III) CONTAINING N, N'-TETRAMETHYLENEBIS (SALICYLIDENEIMINE) AND BIDENTATE LIGANDS
SYAMAL, A
GHANEKAR, VD
CURRENT SCIENCE, 1976, 45 (15): : 547 - 549
[38] SPECTROSCOPIC BEHAVIOR OF A NEW FAMILY OF MIXED-LIGAND IRIDIUM(III) COMPLEXES
SANDRINI, D
MAESTRI, M
ZIESSEL, R
INORGANICA CHIMICA ACTA, 1989, 163 (02) : 177 - 180
[39] Mixed-ligand Complexes of Ruthenium(II) and Iridium(III) with Triphenylphosphine and Thiocarbohydrazide
Pandey, R. N.
Gautam, K. V.
ASIAN JOURNAL OF CHEMISTRY, 2011, 23 (10) : 4517 - 4519
[40] H-2 NMR-SPECTRA FOR MIXED-LIGAND CHROMIUM(III) COMPLEXES WITH DEUTERIATED MALONATO AND ACETYLACETONATO LIGANDS
KAIZAKI, S
HIROTA, N
TANAKA, C
TANO, J
LAN, LX
LEGG, JI
INORGANICA CHIMICA ACTA, 1992, 197 (02) : 185 - 192

← 1 2 3 4 5 →