Kinetics of Formation of Ruddlesden-Popper Phases: I. Mechanism of La2SrAl2O7 Formation

被引:0
作者
I. A. Zvereva
V. F. Popova
D. A. Vagapov
A. M. Toikka
V. V. Gusarov
机构
[1] St. Petersburg State University,Grebenshchikov Institute of Silicate Chemistry
[2] Russian Academy of Sciences,undefined
来源
Russian Journal of General Chemistry | 2001年 / 71卷
关键词
Melting Point; Perovskite; Critical Temperature; Layered Structure; Phase Formation;
D O I
暂无
中图分类号
学科分类号
摘要
Phase formation in the La2O3-SrO-Al2O3 system was studied. Formation of the perovskite LaAlO3 structure and the perovskite-like LaSrAlO4 and La2SrAl2O7 layered structures in solid-phase chemical reactions is activated only after reaching certain critical temperatures which correlate with the temperatures of of the transition of intergranular formations to the liquid-like state (melting points of two-dimensional nonautonomous phases).
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页码:1181 / 1185
页数:4
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