Phase and extraction equilibria in the antipirin-pyrocatechol-water system

被引:0
作者
S. A. Denisova
O. S. Kudryashova
A. E. Lesnov
E. A. Sazonova
机构
[1] Perm State University,Natural Science Institute
[2] Ural Branch,Institute of Technical Chemistry
[3] Russian Academy of Sciences,undefined
来源
Russian Journal of General Chemistry | 2007年 / 77卷
关键词
Scandium; Pyrocatechol; Extraction Equilibrium; Conductometric Titration; Crystallization Field;
D O I
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中图分类号
学科分类号
摘要
Solubility isotherms of the antipirin-pyrocatechol-water ternary system at 25 and 50°C were constructed. A field where two liquid phases are present in equilibrium which results from the protolytic interaction between the components was revealed. The various-composition chemical compounds that formed were isolated preparatively. Interphase distribution of a series of metal ions was studied. The half-extraction pHs of rare-earth metals were found to be linearly related to their ionic radii.
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页码:1855 / 1858
页数:3
相关论文
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[2]  
Petrov B.I.(1985)undefined Zh. Prikl. Khim. 58 2194-undefined
[3]  
Afendikova G.Yu.(undefined)undefined undefined undefined undefined-undefined