Synthesis and Structure of Tetraphenylantimony Nitrite

被引：0

作者：

V. V. Sharutin

A. P. Pakusina

I. V. Egorova

T. P. Platonova

B. V. Bukvetskii

D. Yu. Popov

机构：

[1] Blagoveshchensk State Pedagogical University,Far East Division, Russian Academy of Sciences

[2] Institute of Chemistry,undefined

来源：

Russian Journal of Coordination Chemistry | 2002年 / 28卷

关键词：

Oxygen; Physical Chemistry; Toluene; Nitrite; Oxygen Atom;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Tetraphenylantimony nitrite was synthesized by reacting pentaphenylantimony with triphenylantimony dinitrite at a molar ratio of 1 : 1 in toluene, and its structure was determined using X-ray diffraction analysis. The Sb atom is coordinated to the oxygen atom of the axial nitrite group to form a trigonal bipyramid. The Sb–C(Ph)eq distances vary within the 2.103–2.111(3) Å range, and the S–O(1) and Sb–C(41) bond lengths are equal to 2.386(3) and 2.156(3) Å, respectively. The Sb...N distance and the axial C(41)SbO(1) angle are equal to 3.133(4) Å and 174.7(1)°, respectively.

引用

页码：827 / 830

页数：3

共 24 条

[1]

Sharutin V.V.(1996)undefined Zh. Obshch. Khim. 66 1755-undefined

[2]

Senchurin V.S.(1997)undefined Zh. Obshch. Khim. 67 1531-undefined

[3]

Sharutina O.K.(1997)undefined Zh. Obshch. Khim. 67 1536-undefined

[4]

Sharutin V.V.(1999)undefined Zh. Obshch. Khim. 69 1979-undefined

[5]

Sharutina O.K.(1989)undefined Phosphorus, Sulfur Silicon Relat. Elem. 45 23-undefined

[6]

Panova L.P.(1997)undefined J. Organomet. Chem. 536-537 87-undefined

[7]

Bel'skii V.K.(1991)undefined Zh. Neorg. Khim. 36 3015-undefined

[8]

Sharutin V.V.(2000)undefined Zh. Obshch. Khim. 70 931-undefined

[9]

Sharutina O.K.(undefined)undefined undefined undefined undefined-undefined

[10]

Pakusina A.P.(undefined)undefined undefined undefined undefined-undefined

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