Comparison of the specific adsorption of sulfate (HSO4−) ions on Cr and Cr2O3

被引:0
作者
G. Horányi
机构
[1] Hungarian Academy of Sciences,Research Laboratory of Materials and Environmental Chemistry, Chemical Research Center
来源
Journal of Solid State Electrochemistry | 2004年 / 8卷
关键词
Chromium; Chromium oxide; Radiotracer technique; Specific adsorption; Sulfate ions;
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学科分类号
摘要
The specific adsorption of sulfate ions on powdered Cr was studied by a radiotracer technique using 35S-labeled sulfuric acid in low concentration (c<10−3 mol dm−3) in the presence of a large excess of perchlorate supporting electrolyte. The pH and concentration dependence were determined. On the basis of a comparison of the results obtained for Cr2O3 and Cr, it can be assumed that, similar to other metals, the overall sorption behavior of Cr is determined by the protective oxide film present on the surface.
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页码:215 / 217
页数:2
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